Twisted Bonds (The Camorra Chronicles Book 4)

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Kanawati, B., Genest, A., Schmitt-Kopplin, P. & Lenoir, D. Bis-dibenzo[a.i]fluorenylidene, does it exist as stable 1,2-diradical? J. Mol. Model. 18, 5089–5095 (2012).

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Grimme, S., Antony, J., Ehrlich, S. & Krieg, H. A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu. J. Chem. Phys. 132, 154104 (2010). For a moment I only stared at the man before me. He looked so relaxed, so … approachable. Not harmless, not nice, but not as monstrous as his words made him sound. They reminded me of his nature. Maybe that was why he had the tattoos of roaring flames and screaming grimaces, as a warning of what lay beneath his beautiful exterior. “That sounds as if you and Remo admire Luca.” Nino’s dark brows pulled together, his fingers on my wrist tightening once more. “You didn’t know?”

Kawata, S. et al. Controlling the excited-state energy levels of 9,9′-bifluorenylidene derivatives by twisting their structure to attaining singlet fission character in organic photovoltaics. J. Mater. Chem. C 5, 4909–4914 (2017).

The Camorra Chronicles Series by Cora Reilly - Goodreads

Biedermann, P. U. & Agranat, I. Stereochemistry of bistricyclic aromatic enes and related polycyclic systems. Top. Curr. Chem. 350, 177–278 (2014). Dugave, C. & Demange, L. Cis− trans isomerization of organic molecules and biomolecules: Implications and applications. Chem. Rev. 103, 2475–2532 (2003).Régimbald-Krnel, M. & Wentrup, C. On the di-1-naphthylcarbene−dibenzofluorene rearrangement and the ethylenization of diarylcarbinols. J. Org. Chem. 63, 8417–8423 (1998).

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Y.T.W. conceived the idea and designed the experiments. H.W.K. undertook the synthesis and analysis of all compounds, as well as the measurement of photoabsorption and electrochemical properties. M.H.C. directed investigations of magnetic properties. Y.C.L. conducted the ESR and SQUID measurements. M.J.C. provided guidance for the computational studies, while C.T.H. and W.K.S. executed the DFT calculations. P.T.C. and S.D.Y. supervised photodynamic investigations. B.H.C., C.H.L. and Y.C.W. measured the TA spectra and analyzed data. M.H.C, P.T.C. and Y.T.W. co-wrote the manuscript. All authors discussed the results and commented on the manuscript. Corresponding authors The temperature-dependent magnetic susceptibilities ( χ M) for powdered samples of 1a, 1b, 1c, 2, and 3 were obtained using a SQUID magnetometer. The χ M T curves for all compounds exhibited decreasing trends when the temperature was decreased to 2 K, suggesting a singlet ground state (Supplementary Fig. 15). The value of Δ E ST was estimated by fitting the temperature-dependent χ M T data using the Bleaney-Bowers equation 44. Satisfactory fits were achieved, and 1b exhibited the smallest Δ E ST (3.65 kcal/mol) compared to the other compounds (4.32–5.68 kcal/mol, Table 2). Barclay, T. M. et al. The heterocyclic diradical benzo-1,2:4,5-bis(1,3,2-dithiazolyl). electronic, molecular and solid state structure. J. Am. Chem. Soc. 119, 2633–2641 (1997). Molins, E., Miravitlles, C., Espinosa, E. & Ballester, M. 1,1’,3,3’,6,6’,8,8’-Octachloro-9,9’-bifluorenylidene and perchloro-9,9’-bifluorenylidene, two exceedingly twisted ethylenes. J. Org. Chem. 67, 7175–7178 (2002).

Kiara always wanted a loving family she could take care of. She never thought she’d find it with the Falcones.

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I shrugged. “I know that now, or I think I do. But when I was a young girl, Father always blamed me or Mother when something went wrong, and so did my brothers even when they had messed up, and I believed them. If you’re told something often enough, you just take it for the truth. When Father hit me, I thought I deserved it.”Compounds 1a– d, 2, and 3 were prepared from 7a– 7d, 8 and 9, respectively, by the tBuOK-mediated oxidative dehydrogenation. The reaction conditions were substrate dependent. For details, see Supplementary Information. Characterization